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The last theory I heard was that fish developed calcium deposits in order to move up river deltas into fresh water. Calcium is important for muscle function and you would have to bring a stable supply with you to survive.

The fact that mammals still cycle calcium in and out of their bones to manage blood chemistry was as I recall used to support that theory.

This is something that I think about, we have CO2 contributing to acidity, but what are nature's ways of providing alcalinity??
calcium carbonate
which is CaO + CO2, so that doesn't answer the question too much