Look into IDEO (a world-class design firm) and their prototyping methods. They're really good at getting to the core of an idea with the limited materials available (as an example: they prototyped a surgeon's tool with a sharpie and some tape.)
DIY with a screen recording product like Telestream/ScreenFlow(Mac) or TechSmith/Camtasia(PC). Record a walk through of your web app (or mocked up screens), while also recording yourself doing the voice over.
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