The formatting and styling is a little dated and claustrophobic, but I always liked how thoroughly (with plentiful links to convenient test examples and a dev console) the New York Times documented their APIs: http://developer.nytimes.com/docs/congress_api
I like the way the Stripe documentation is done. I've seen other tools/libs use a similar format but I'm not sure what the underlying doc generator is.
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[ 3.5 ms ] story [ 28.1 ms ] threadAlso, although not an API, the diagrams in the SQLite docs are extremely helpful in structuring statements: http://www.sqlite.org/lang_createtable.html