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Perhaps it's a topological insulator, so that the bulk conducts but you'd never know it because the surface doesn't.

I'm a total noob, so if that is correct it's a miracle.

The article touches on that:

"But this is no garden-variety insulator. Not only does its insulating behavior arise from strong correlations between its electrons, but in the past five years, mounting evidence has suggested that it is a “topological insulator” at low temperatures, a material that resists the flow of electricity through its three-dimensional bulk, while conducting electricity along its two-dimensional surfaces."

All conductors only conduct along their surface...unless I'm mistaken.
No, generally a thicker cable is a better conductor because its resistance is lower. If it were merely a matter of surface conductivity this wouldn't necessarily be true. However, internal conductivity and surface conductivity can be affected by magnetic fields:

http://faculty.wwu.edu/vawter/physicsnet/Topics/Gauss/IdealC...

There is also a tendency for currents to creep towards the surface of the conductor at high frequencies, see [1], although this is ultimately also caused by internally generated electromagnetic fields.

[1] https://en.wikipedia.org/wiki/Skin_effect

"...And yet, SMB6 does not neatly fit that category either."
This could have applications on quantum computers & new type of transistors ! HYPE :) !
"Charcoal briquette cracks 8192-bit RSA keys in seconds!"
(comment deleted)
I assume those "quantum oscillation" measurements were electron cyclotron resonance measurements[1].

Also there is an other type of non-conventional insulator which is considered to be well understood: the Mott-insulator[2]. It really doesn't fit in here as a candidate since one wouldn't expect cyclotron resonance from this model in the insulating regime. However it's a good learning example of strongly correlated electrons in materials.

[1]https://en.wikipedia.org/wiki/Electron_cyclotron_resonance#I... [2]https://en.wikipedia.org/wiki/Mott_insulator